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09-16
2023
Elucidating the Underlying Reactivities of Alternating Curren...
? ? Qiao Zhang, Hsin Jung Tsai, Fuhua Li, Zhiming Wei, Qinye He, Jie Ding, Yuhang Liu, Zih-Yi Lin, Xiaoju Yang, Zhaoyang Chen, Fangxin Hu, Xuan Yang, Qing Tang, Hong Bin Yang, Sung-Fu Hung, Yueming Zhai.Angew. Chem. Int. Ed.(翟月明)Abstract:? ? ? ? The? Single-atom catalysts exhibit superior CO2-to-CO catalytic activity, but poor kinetics of proton-coupled electron transfer (PCET) steps still limit ...
09-08
2023
Elucidating the Underlying Reactivities of Alternating Curren...
? ? Qiongqiong Wan, Kaixiang Chen, Xin Dong, Xianqin Ruan, Prof. Hong Yi, Prof. Suming Chen.Angew. Chem. Int. Ed.(陈素明、易红)Abstract:? ? ? ? The?Alternating current (AC) electrolysis is an emerging field in synthetic chemistry, however its mechanistic studies are challenged by the effective characterization of the elusive intermediate processes. Herein, we develop an operando electrochemical ...
07-25
2023
Single Nanoparticle-Based Nanomachining for Fabrication of Un...
? ? Longfei Miao, Bintong Huang, Hui Fang, Jia Chai, Ze Liu, Yueming Zhai.Advanced Materials(翟月明)Abstract:? ? ? ? The structure of nanomaterials and nanodevices determines their functionality and applications. A single uniform nanochannel with a high aspect ratio is an attractive structure due to its unique rigid structures, easy preparation and diverse pore structures that hold significant promising ...
07-25
2023
A facile synthetic approach based on thieno[3,4-c]pyrrole-4,6...
? ? Lin-Yong Xu, Yuan Gao,Wei Wang, Yiming Shao, Mingxia Chen, Xinrong Yang, Yuang Fu, Meimei Zhang, Xinhui Lu, Rui Sun and Jie Min.Energy & Environmental Science(闵杰)Abstract:? ? ? ? To realize the application of organic solar cells (OSCs), emphasis must be placed on reducing material cost, which is one of the golden triangle elements. One key strategy to address this issue is to optimize the ...
07-25
2023
Axial chirality reversal and enantioselective access to Si-st...
? ? ? ? Chenyu Jin,Xiaoqian He,Shaowei Chen,Zhuanzhuan Guo,Yu Lan,Xiao Shen.Chem(沈晓、蓝宇)Abstract:? ? ? ? Selective hydrosilylation of 1,3-enynes is challenging because of the competing 1,2-, 1,4-, 4,3-hydrosilylation and sequential double hydrosilylation. Herein, we report a Cu-catalyzed enantioselective 1,4-hydrosilylation of 1,3-enynes. The reaction is amenable not only to preparing chiral ...
07-22
2023
Cobalt-catalysed allylic fluoroalkylation of terpenes
Shengchun Wang,Demin Ren,Zhao Liu,Dali Yang,Pengjie Wang,Yiming Gao,Xiaotian Qi &Aiwen Lei.Nature Synthesis.(雷爱文)Abstract:? ? ? ? Developing practical strategies to produce high-value chemicals, such as pharmacologically active molecules, from bulk starting materials is an ongoing challenge. One potential route to this goal is the C(sp3)–H fluoroalkylation of natural products, made possible ...
07-12
2023
Single Nanoparticle-Based Nanomachining for Fabrication of Un...
? ? Weiyu Kong, Yang Bao, Liguo Lu, Zhipeng Han, Yifan Zhong, Dr. Ran Zhang, Dr. Yuqiang Li, Prof.?Dr. Guoyin Yin.Angewandte Chemie International Edition.(阴国。〢bstract:? ? ? ? While chain-walking stimulates wide interest in both polymerization and organic synthesis, site- and stereoselective control of chain-walking on rings is still a challenging task in the realm of organometallic catalysis....
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